Effect of ageing process on bisphenol A sorption and retention in agricultural soils amended with biochar.

The ageing of biochar and organic pollutant itself in soils can both influence the retention of organic pollutant in field soils. In this study, column experiments were adopted to determine the effect of ageing process on bisphenol A (BPA) sorption and retention in two typical Chinese agricultural soils with lychee branch biochar added. The effect of biochar ageing on soil organic matter (SOM) was specially investigated. Experimental results showed that the addition of biochar significantly increased the condensation and rigid of SOM, which could further increase with biochar ageing in soils. As a result, the addition of biochar significantly increased BPA sorption capacity (5.86 times and 3.30 times) and retention rate (13.60 times and 4.47 times) in fluvo-aquic soil and phaeozem respectively, while BPA sorption capacity and retention rate decreased obviously after biochar ageing in the two soils for 2 months as compared with the freshly incorporated biochar treatments, which may be attributed to the surface coverage and/or pore blockage of some sorption sites owning to DOC. With biochar incorporated, 2 months of BPA ageing increased BPA retention rate by about 4.50 times in both soils as compared with BPA newly spiked treatments. The results of this study could provide important parameters for prediction and control of organic pollutants such as BPA in soils.