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(天门冬科)的植物化学成分分析及对(窃蠹科)成虫的杀虫活性。

Phytochemical profile and insecticidal activity of (Asparagaceae) against adults of (Anobiidae).

机构信息

Dipartimento di Scienze e Tecnologie Biologiche, Chimiche e Farmaceutiche (STEBICEF), Università degli Studi di Palermo, Palermo, Italy.

Dipartimento di Scienze Agrarie, Alimentari e Forestali (SAAF), Università degli Studi di Palermo, Palermo, Italy.

出版信息

Nat Prod Res. 2021 Nov;35(22):4468-4478. doi: 10.1080/14786419.2020.1729154. Epub 2020 Mar 12.

Abstract

Chemical and spectroscopic investigation of the bulbs of resulted in the isolation of one known flavonol (), never isolated from this plant species, and of three previously described steroidal saponins (), but whose configuration at their stereogenic centres was not clearly determined. By mean of H NMR, C NMR, nuclear overhauser effects (NOE) and two-dimensional NMR spectra the full stereochemical structures of compounds were proved and all the H and C signals were assigned. Furthermore, the methanol and butanol extracts of were tested against adults of beetles. Despite the non-significant results regarding the repellent activity and contact toxicity, promising results were obtained from the feeding tests.

摘要

对 鳞茎的化学和光谱研究导致分离出一种已知的类黄酮(),从未从该植物物种中分离出来,以及三种以前描述的甾体皂苷(),但其手性中心的构型尚未明确确定。通过 H NMR、C NMR、核奥弗豪瑟效应(NOE)和二维 NMR 光谱,证明了化合物的全立体化学结构,并对所有 H 和 C 信号进行了分配。此外,还对 甲醇和丁醇提取物进行了测试,以评估其对 成虫的驱避活性和接触毒性。尽管驱避活性和接触毒性的结果不显著,但在摄食试验中获得了有希望的结果。

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