Čopič Martin, Mertelj Alenka
J. Stefan Institute, SI-1000 Ljubljana, Slovenia.
Faculty of Mathematics and Physics, University of Ljubljana, SI-1000 Ljubljana, Slovenia.
Phys Rev E. 2020 Feb;101(2-1):022704. doi: 10.1103/PhysRevE.101.022704.
The twist-bend nematic phase (N_{TB}) is characterized by a conically twisting director and by a dramatic softening of the bend elastic constant before the transition to the N_{TB} phase. In the recently found splay nematic phase (N_{S}) the splay elastic constant tends to zero, resulting in a splay modulation perpendicular to the director. We model both phases with a single Q-tensor free energy including a term that breaks the degeneracy between the splay and bend elastic constant, and a flexoelectric term coupling the divergence of the Q-tensor with polarization. The N_{TB} or N_{S} phase is obtained by a change of sign of one elastic parameter. Measured elastic constants show that the N-N_{TB} transition is mainly driven by the increase of the nematic order, while the N_{S} transition is due to flexoelectric coupling.
扭曲弯曲向列相(NTB)的特征在于锥形扭曲的指向矢,以及在转变为NTB相之前弯曲弹性常数的显著软化。在最近发现的展向向列相(NS)中,展向弹性常数趋于零,导致垂直于指向矢的展向调制。我们用一个单一的Q张量自由能对这两个相进行建模,该自由能包括一个打破展向和弯曲弹性常数简并的项,以及一个将Q张量的散度与极化耦合的挠曲电项。通过改变一个弹性参数的符号可得到NTB或NS相。测量得到的弹性常数表明,N-NTB转变主要由向列序的增加驱动,而NS转变则归因于挠曲电耦合。