Nitti Andrea, Pasini Dario
Department of Chemistry and INSTM Research Unit, University of Pavia, Via Taramelli 12, Pavia, 27100, Italy.
Adv Mater. 2020 Oct;32(41):e1908021. doi: 10.1002/adma.201908021. Epub 2020 Mar 16.
Chirality is becoming increasingly important in the design of organic materials with functional properties, when bulk anisotropy is needed. In the past decades, a plethora of chiral organic materials have been studied and developed. Nanostructures have brought substantial advancement to the realization of organic-molecule-based devices, and the possibilities for solid-state light emission are very promising in view of potential applications. Scientific approaches to the realization of chiral emissive materials are indeed growing exponentially. The chiral nanostructures discussed are related both to the way in which luminescence is generated and the way in which it is detected. As to the former, the focus will be on organic chromophores with aggregation-induced emission properties, so that emission is present, or at least largely amplified, when the molecules are in the aggregated state. As to the latter, the focus will be on the ability and a quantitative comparison of organic nanostructures capable of circularly polarized emission.
当需要体各向异性时,手性在具有功能特性的有机材料设计中变得越来越重要。在过去几十年中,人们研究并开发了大量的手性有机材料。纳米结构为基于有机分子的器件的实现带来了实质性进展,鉴于潜在应用,固态发光的可能性非常广阔。实现手性发光材料的科学方法确实在呈指数级增长。所讨论的手性纳米结构既与发光产生的方式有关,也与发光检测的方式有关。对于前者,重点将放在具有聚集诱导发光特性的有机发色团上,以便当分子处于聚集状态时存在发射,或者至少发射被大幅放大。对于后者,重点将放在能够进行圆偏振发射的有机纳米结构的能力及定量比较上。