Sun Xiaohao, Liu Debao, Zhou Weiwei, Nomura Naoyuki, Tsutsumi Yusuke, Hanawa Takao
School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China; Graduate School of Engineering, Department of Materials Processing, Tohoku University, Sendai, 9808579, Miyagi, Japan.
School of Materials Science and Engineering, Tianjin University of Technology, Tianjin, 300384, China.
J Mech Behav Biomed Mater. 2020 Apr;104:103655. doi: 10.1016/j.jmbbm.2020.103655. Epub 2020 Jan 27.
In order to solve the artifact problem in magnetic resonance images, a low magnetic Zr-1Mo(wt%) alloy with high mechanical performance was successfully fabricated by laser powder bed fusion (L-PBF) using gas-atomized Zr-1Mo alloy powder. The as-built Zr-1Mo alloy showed superior strength and elongation compared to the as-cast Zr-1Mo alloy due to grain refinement and the inexistence of large casting defects. The microstructure of L-PBF-processed Zr-1Mo alloy builds was not sensitive to process parameters. On the other hand, morphology and distribution of defects, interstitials concentration, and crystallographic orientation comprehensively influenced the mechanical properties of the builds. Increasing interstitials concentration caused by increasing energy density render to increasing strength. Large pores caused by balling effect lead to a severe decrease of both strength and ductility of builds using high energy density (over 70.3 J·mm) and high scanning speed (1050/1200 mm·s). On the contrary, spherical pores possessing several microns in size has much less effect on mechanical properties than the large-size pores. There are two kinds of texture({1 1 0} texture and {1 1 0}+{1 0 2} bi-texture) were confirmed in this study. {1 1 0} texture contributed to the slight increase of elongation with increasing energy density in low scanning speed case (600/750 mm·s) and the superior elongation of low scanning speed specimens compare to that of high scanning speed specimens in medium energy density range (about 48 J·mm). From the viewpoints of the ultimate tensile strength(UTS) and elongation, it was found that an energy density of 84.4 mm·s with a scanning speed of 600 mm·s is preferable for the L-PBF-processed Zr-1Mo alloy in this study. These experimental results may provide direct guidelines regarding the applicability of Zr-1Mo alloy fabricated by L-PBF for biomedical applications.
为了解决磁共振图像中的伪影问题,采用气雾化Zr-1Mo合金粉末,通过激光粉末床熔融(L-PBF)成功制备了具有高力学性能的低磁性Zr-1Mo(wt%)合金。由于晶粒细化且不存在大的铸造缺陷,增材制造态Zr-1Mo合金与铸造态Zr-1Mo合金相比表现出优异的强度和伸长率。L-PBF工艺制备的Zr-1Mo合金构件的微观结构对工艺参数不敏感。另一方面,缺陷的形态和分布、间隙原子浓度以及晶体取向综合影响了构件的力学性能。能量密度增加导致间隙原子浓度增加,从而使强度增加。由球化效应引起的大孔隙会导致使用高能量密度(超过70.3 J·mm)和高扫描速度(1050/1200 mm·s)的构件的强度和延展性严重下降。相反,尺寸为几微米的球形孔隙对力学性能的影响远小于大尺寸孔隙。本研究中确认了两种织构({1 1 0}织构和{1 1 0}+{1 0 2}双织构)。在低扫描速度(600/750 mm·s)情况下,{1 1 0}织构导致伸长率随能量密度增加而略有增加,并且在中等能量密度范围(约48 J·mm)内,低扫描速度试样的伸长率优于高扫描速度试样。从极限抗拉强度(UTS)和伸长率的角度来看,本研究发现对于L-PBF工艺制备的Zr-1Mo合金,扫描速度为600 mm·s时能量密度为84.4 mm·s是较为理想的。这些实验结果可为L-PBF制备的Zr-1Mo合金在生物医学应用中的适用性提供直接指导。