State Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Medical College, Xiamen University, Xiamen 361005, China.
Molecules. 2020 Mar 12;25(6):1286. doi: 10.3390/molecules25061286.
The mixed-ligand copper(II) iminodiacetates [Cu(ida)(2-mim)(HO)]·HO (), [Cu(ida)(2-mim)]·2HO (), [Cu(ida)(2-mim)(HO)]·4.5nHO (), and [Cu(ida)(2-mim)]·nHO () (Hida = iminodiacetic acid, 2-mim = 2-methylimidazole) were obtained from neutral or alkaline solutions at different temperatures. The novel complex contains very small holes with diameters of 2.9 Å, which can adsorb O selectively and reversibly between 1.89 to 29.90 bars, compared with the different gases of N, H, CO, and CH. This complex is stable up to 150 °C based on thermal analyses and XRD patterns. The four complexes show catalytic activities that facilitate the conversion of cyclohexane to cyclohexanol and cyclohexanone with hydrogen peroxide in a solution. The total conversion is 31% for .
混合配体铜（II）亚氨基二乙酸盐 [Cu(ida)(2-mim)(HO)]·HO (), [Cu(ida)(2-mim)]·2HO (), [Cu(ida)(2-mim)(HO)]·4.5nHO (), 和 [Cu(ida)(2-mim)]·nHO () (Hida = 亚氨基二乙酸，2-mim = 2-甲基咪唑) 是从不同温度的中性或碱性溶液中获得的。新型配合物 包含非常小的孔，直径为 2.9 Å，可以在 1.89 至 29.90 巴之间选择性和可逆地吸附 O，与不同的气体 N、H、CO 和 CH 相比。该配合物基于热分析和 XRD 图谱稳定至 150°C。这四个配合物在溶液中具有催化活性，可促进环己烷转化为环己醇和环己酮与过氧化氢。 的总转化率为 31%。
