Effect of soil pH on the transport, fractionation, and oxidation of chromium(III).

This work was conducted to study the effect of soil pH (4.0, 6.0, and 8.0) on the transport, fractionation, and oxidation of trivalent chromium [Cr(III)]. Variation in pH altered soil chemical and mineralogical properties such as zeta potential, cation exchange capacity and redox potential of natural soil. Breakthrough curves and batch sorption experiments coupled with fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analyses demonstrated that the easy mobility of Cr(III) in pH 4.0 soil was dominated by the limited coordination effect. The high retention of Cr(III) in pH 8.0 soil was mainly ascribed to the hydrolysis. Incubation experiments indicated that the proportions of Cr in exchangeable fraction decreased with increasing of soil pH and incubation time, and kinetics analysis revealed that the time dependent transformation was controlled by mass transfer and chemical processes (e.g., hydrolysis, ion association). The XPS confirmed the oxidation of Cr(III) in pH 8.0 soil during the incubation period. Furthermore, the content of toxic hexavalent chromium [Cr(VI)] was positively associated with time and initial concentration of Cr(III) released. These results revealed the hazardousness of Cr(III) in soil contaminated simultaneously by inorganic acid and alkali.