Guildner Leslie A, Edsinger Robert E
Institute for Basic Standards, National Bureau of Standards, Washington, D.C. 20234.
J Res Natl Bur Stand A Phys Chem. 1973 Jul-Aug;77A(4):383-389. doi: 10.6028/jres.077A.026.
The investigation of the effects of sorption in a gas thermometer used to realize the Thermodynamic Kelvin Temperature Scale has been continued. By eliminating sorbable material more completely from the gas thermometer, we attained higher gas purity. So little contaminant remained that further cleanup produced no significant effect on the values of thermodynamic temperatures measured between 0 °C and 142 °C. The results are presented by giving the differences between the values on the thermodynamic scale and the International Practical Temperature Scale of 1968. The value of the steam point was determined to be 99.970 °C(therm) with an uncertainty of ±3.5 mK at the 99 percent confidence level (based on 3 times the estimate of the standard deviation).
对用于实现热力学开尔文温标的气体温度计中吸附效应的研究仍在继续。通过更彻底地从气体温度计中去除可吸附物质,我们获得了更高的气体纯度。残留的污染物极少,以至于进一步净化对0°C至142°C之间测量的热力学温度值没有显著影响。通过给出热力学温标值与1968年国际实用温标值之间的差异来呈现结果。在99%置信水平下(基于标准偏差估计值的3倍),确定蒸汽点的值为99.970°C(热力学),不确定度为±3.5 mK。