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压缩和液化甲烷的比热容\(C_p\)和\(C_v\)

The Specific Heats, , and , of Compressed and Liquefied Methane.

作者信息

Younglove B A

机构信息

Institute for Basic Standards, National Bureau of Standards, Boulder, Colorado 80302.

出版信息

J Res Natl Bur Stand A Phys Chem. 1974 May-Jun;78A(3):401-410. doi: 10.6028/jres.078A.023.

DOI:10.6028/jres.078A.023
PMID:32189790
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6742817/
Abstract

The specific heats, , of saturated liquid methane have been measured at 66 temperatures in the temperature range 95-187 K. The specific heats at constant volume, , have been measured at 20 densities ranging from 0.8 to 2.8 times the critical density, at temperatures between 91 and 300 K, and at pressures to 330 bar (at 280 states in all). The uncertainty of most of the measurements is estimated to be less than 0.5 percent, except near the critical point. These measurements were performed primarily to provide input data for accurate thermodynamic properties data calculations for liquid methane. They are believed to be the most comprehensive specific heat measurements available for pure compressed gaseous and liquid methane.

摘要

已在95 - 187K的温度范围内的66个温度点测量了饱和液态甲烷的比热容 。在91至300K的温度、高达330巴的压力下(总共280个状态),针对20种密度(范围为临界密度的0.8至2.8倍)测量了定容比热容 。除临界点附近外,大多数测量的不确定度估计小于0.5%。进行这些测量主要是为液态甲烷精确的热力学性质数据计算提供输入数据。据信它们是可用于纯压缩气态和液态甲烷的最全面的比热容测量数据。

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引用本文的文献

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3
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J Res Natl Inst Stand Technol. 1991 Nov-Dec;96(6):725-740. doi: 10.6028/jres.096.047.

本文引用的文献

1
Densities of Compressed Liquid Methane, and the Equation of State.压缩液态甲烷的密度及状态方程
J Res Natl Bur Stand A Phys Chem. 1972 Mar-Apr;76A(2):81-101. doi: 10.6028/jres.076A.010.
2
Specific Heats, C, of Compressed Liquid and Gaseous Fluorine.压缩液态和气态氟的比热容C
J Res Natl Bur Stand A Phys Chem. 1970 Sep-Oct;74A(5):661-665. doi: 10.6028/jres.074A.054.
3
Specific Heats of Fluorine at Coexistence.共存状态下氟的比热
J Res Natl Bur Stand A Phys Chem. 1970 Jul-Aug;74A(4):499-505. doi: 10.6028/jres.074A.040.
4
Specific Heats C of Fluid Oxygen from the Triple Point to 300 K at Pressures to 350 Atmospheres.从三相点到300K、压力达350个大气压时液氧的比热C
J Res Natl Bur Stand A Phys Chem. 1969 Jan-Feb;73A(1):15-24. doi: 10.6028/jres.073A.002.
5
Specific Heats of Oxygen at Coexistence.共存状态下氧气的比热
J Res Natl Bur Stand A Phys Chem. 1969 Jan-Feb;73A(1):1-13. doi: 10.6028/jres.073A.001.
6
Heat capacity of a two-phase system, with applications to vapor corrections in calorimetry.
J Res Natl Bur Stand (1934). 1946 Feb;36:111-8. doi: 10.6028/jres.036.003.