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通过多种外部刺激实现新型星状发光体的荧光到多色磷光的相互转换。

Fluorescence to multi-colored phosphorescence interconversion of a novel, asterisk-shaped luminogen via multiple external stimuli.

机构信息

Henan Key Laboratory of Photovoltaic Materials, Henan University, 475004 Kaifeng, P. R. China.

出版信息

Chem Commun (Camb). 2020 Apr 21;56(31):4336-4339. doi: 10.1039/d0cc00371a. Epub 2020 Mar 19.

DOI:10.1039/d0cc00371a
PMID:32191237
Abstract

We designed and characterized an asterisk-shaped luminogen, hexakis(pyridin-4-ylthio)benzene (HPTB). Via external stimuli such as CHOH, H, and Ag, HPTB's luminogenic character transitioned from blue fluorescence to green, yellow, and orange phosphorescence. Results showed that this interconversion was a reversible process that was also reproducible in liquid and in the solid state.

摘要

我们设计并表征了一种星形发光体,六(4-吡啶基硫基)苯(HPTB)。通过 CHOH、H 和 Ag 等外部刺激,HPTB 的发光特性从蓝色荧光转变为绿色、黄色和橙色磷光。结果表明,这种互变是一个可逆过程,在液体和固态中也具有可重复性。

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