三氯化钛的生成热
Heat of Formation of Titanium Trichloride.
作者信息
Johnson Walter H, Gilliland Alexis A, Prosen Edward J
出版信息
J Res Natl Bur Stand A Phys Chem. 1960 Nov-Dec;64A(6):515-519. doi: 10.6028/jres.064A.051. Epub 1960 Dec 1.
Abstract
A calorimetric comparison of the heat of hydrolysis of TiCl(liq) with the heat of oxidation and hydrolysis of TiCl(c) has been made. The following value is reported for the combination of these data according to the process: A combination of this value with -192.3 ±0.7 kcal/mole for the heat of formation of TiCl(liq) and with the standard heats of formation of HCl(g) and HI(g) gives for TiCl(c), ΔHf°(25 °C) = -172.4±0.8 kcal/mole.
摘要
已对液态TiCl水解热与固态TiCl氧化热及水解热进行了量热比较。根据以下过程报告了这些数据组合的以下值：将该值与液态TiCl生成热的-192.3±0.7千卡/摩尔以及HCl(g)和HI(g)的标准生成热相结合，得出固态TiCl的ΔHf°(25 °C) = -172.4±0.8千卡/摩尔。
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本文引用的文献
1
Heat of Formation of Titanium Tetraiodide.四碘化钛的生成热
J Res Natl Bur Stand A Phys Chem. 1959 Sep-Oct;63A(2):161-166. doi: 10.6028/jres.063A.009. Epub 1959 Oct 1.
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