Key Laboratory of New Processing Technology for Nonferrous Metal and Materials (Ministry of Education), College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, PR China.
Key Laboratory of New Processing Technology for Nonferrous Metal and Materials (Ministry of Education), College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, PR China.
Int J Biol Macromol. 2020 Jul 1;154:974-980. doi: 10.1016/j.ijbiomac.2020.03.151. Epub 2020 Mar 17.
Despite impressive progress of macromolecular encapsulation technique based on hyperbranched polymer (HP), the use of natural HP for guest encapsulation has rarely been reported. Herein, we present the simple synthesis of amphiphilic PGP-DC from natural peach gum polysaccharide (PGP) and demonstrate that the PGP-DC can be utilized as a robust host for encapsulation of dye molecules from water. The influences of initial dye concentration, dosage of PGP-DC, pH, ionic strength, and encapsulation mode on the encapsulation were systematically studied. The PGP-DC simultaneously exhibited fast encapsulation rate and superior encapsulation capability. Under optimal conditions, the encapsulation capacity of PGP-DC towards methylene blue (MB) (1 mM) can reach as high as 182.67 mg/g, which compares favorably to other separation techniques. Moreover, the MB-encapsulated PGP-DC could be well regenerated in acidic solution. Based on its simple synthetic process, excellent encapsulation performance and fine reusability, the PGP-DC holds great promise for using as a host for practical encapsulation applications.
尽管基于超支化聚合物(HP)的大分子封装技术取得了令人印象深刻的进展,但将天然 HP 用于客体封装的情况却很少有报道。在此,我们从天然桃胶多糖(PGP)简单合成了两亲性 PGP-DC,并证明 PGP-DC 可用作从水中封装染料分子的强大主体。系统研究了初始染料浓度、PGP-DC 用量、pH 值、离子强度和封装模式对封装的影响。PGP-DC 同时表现出快速的封装速率和优异的封装能力。在最佳条件下,PGP-DC 对亚甲蓝(MB)(1mM)的封装容量高达 182.67mg/g,优于其他分离技术。此外,封装 MB 的 PGP-DC 可以在酸性溶液中很好地再生。基于其简单的合成工艺、优异的封装性能和良好的可重复使用性,PGP-DC 有望作为实用封装应用的主体。