Pitois Olivier, Kaddami Asmaa, Langlois Vincent
Lab Navier, Univ Gustave Eiffel, ENPC, CNRS, F-77447 Marne-la-Vallée, France.
Lab Navier, Univ Gustave Eiffel, ENPC, CNRS, F-77447 Marne-la-Vallée, France.
J Colloid Interface Sci. 2020 Jul 1;571:166-173. doi: 10.1016/j.jcis.2020.03.013. Epub 2020 Mar 5.
Although capillary imbibition of solid foams is involved in many industrial applications, general theory for capillary imbibition has never been proved to apply for this specific class of porous materials.
In order to compare accurately experiment and theory we produce solid foam samples with monodisperse pore size distributions and tunable pore volume fraction, and we measure their permeability (Darcy), their capillary pressure and their imbibition rate.
Our findings reveal that the imbibition velocity is qualitatively compatible with the Washburn theory but it is one order of magnitude smaller than the predicted value. This deviation is attributed to the excess time spent by the liquid-gas interface through connections between pores, for which an empirical expression is provided as a function of pore size and solid volume fraction. Our results provide the first step to understand deeply the imbibition process in foams and to predict imbibition rates for various foamed materials.
尽管固体泡沫的毛细管吸渗作用在许多工业应用中都有涉及,但毛细管吸渗的一般理论从未被证明适用于这类特定的多孔材料。
为了准确比较实验和理论,我们制备了具有单分散孔径分布和可调孔隙体积分数的固体泡沫样品,并测量了它们的渗透率(达西)、毛细管压力和吸渗速率。
我们的研究结果表明,吸渗速度在定性上与沃什伯恩理论相符,但比预测值小一个数量级。这种偏差归因于液 - 气界面通过孔隙间连接所花费的额外时间,为此提供了一个作为孔径和固体体积分数函数的经验表达式。我们的结果为深入理解泡沫中的吸渗过程以及预测各种泡沫材料的吸渗速率提供了第一步。