• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

在向日葵籽油作为共底物存在的环境条件下，钴卟啉催化烯烃的仿生需氧环氧化反应。

Biomimetic Aerobic Epoxidation of Alkenes Catalyzed by Cobalt Porphyrin under Ambient Conditions in the Presence of Sunflower Seeds Oil as a Co-Substrate.

作者信息

Jiang Jun, Chen Hong-Yu, Zhou Xian-Tai, Chen Ya-Ju, Xue Can, Ji Hong-Bing

机构信息

Fine Chemical Industry Research Institute, the Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China.

School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, China.

出版信息

ACS Omega. 2020 Mar 2;5(10):4890-4899. doi: 10.1021/acsomega.9b03714. eCollection 2020 Mar 17.

DOI:10.1021/acsomega.9b03714
PMID:32201774
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7081295/
Abstract

In this work, a mild and sustainable catalytic aerobic epoxidation of alkenes catalyzed by cobalt porphyrin was performed in the presence of sunflower seeds oil. Under ambient conditions, the conversion rate of -stilbene reached 99%, and selectivity toward epoxide formation was 88%. The kinetic studies showed that the aerobic epoxidation followed the Michaelis-Menten kinetics. Mass spectroscopy and in situ electron spin resonance indicated that linoleic acid was converted to fatty aldehydes via hydroperoxide intermediates. A plausible mechanism of epoxidation of alkenes was accordingly proposed.

摘要

在这项工作中，在向日葵籽油存在的情况下，进行了钴卟啉催化的温和且可持续的烯烃催化需氧环氧化反应。在环境条件下，反式二苯乙烯的转化率达到99%，环氧化物形成的选择性为88%。动力学研究表明，需氧环氧化遵循米氏动力学。质谱和原位电子自旋共振表明，亚油酸通过氢过氧化物中间体转化为脂肪醛。据此提出了烯烃环氧化的合理机理。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/c881b9326b71/ao9b03714_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/99c08367fd48/ao9b03714_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/381333c2f102/ao9b03714_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/646551641c1f/ao9b03714_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/c1b89f42331b/ao9b03714_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/49558a78395a/ao9b03714_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/c881b9326b71/ao9b03714_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/99c08367fd48/ao9b03714_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/381333c2f102/ao9b03714_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/646551641c1f/ao9b03714_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/c1b89f42331b/ao9b03714_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/49558a78395a/ao9b03714_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0eb4/7081295/c881b9326b71/ao9b03714_0006.jpg

相似文献

1
Biomimetic Aerobic Epoxidation of Alkenes Catalyzed by Cobalt Porphyrin under Ambient Conditions in the Presence of Sunflower Seeds Oil as a Co-Substrate.在向日葵籽油作为共底物存在的环境条件下，钴卟啉催化烯烃的仿生需氧环氧化反应。
ACS Omega. 2020 Mar 2;5(10):4890-4899. doi: 10.1021/acsomega.9b03714. eCollection 2020 Mar 17.
2
Biomimetic iron-catalyzed asymmetric epoxidation of aromatic alkenes by using hydrogen peroxide.使用过氧化氢通过仿生铁催化实现芳香烯烃的不对称环氧化反应。
Chemistry. 2008;14(25):7687-98. doi: 10.1002/chem.200800595.
3
Co6(μ3-OH)6 cluster based coordination polymer as an effective heterogeneous catalyst for aerobic epoxidation of alkenes.基于 Co6(μ3-OH)6 簇的配位聚合物作为一种有效的非均相催化剂用于烯烃的空气氧化环氧化。
Dalton Trans. 2014 Feb 14;43(6):2559-65. doi: 10.1039/c3dt52562g. Epub 2013 Dec 6.
4
Aerobic epoxidation of olefins catalyzed by the cobalt-based metal-organic framework STA-12(Co).钴基金属-有机骨架 STA-12(Co)催化烯烃的需氧环氧化反应。
Chemistry. 2012 Jan 16;18(3):887-98. doi: 10.1002/chem.201101223. Epub 2011 Dec 12.
5
A simple and effective catalytic system for epoxidation of aliphatic terminal alkenes with manganese(II) as the catalyst.一种以锰（II）为催化剂用于脂肪族末端烯烃环氧化的简单且有效的催化体系。
Chemistry. 2008;14(26):7988-96. doi: 10.1002/chem.200800759.
6
Highly efficient and selective epoxidation of alkenes by photochemical oxygenation sensitized by a ruthenium(II) porphyrin with water as both electron and oxygen donor.以水作为电子和氧供体，由钌（II）卟啉敏化的光化学氧化法对烯烃进行高效且选择性的环氧化反应。
J Am Chem Soc. 2003 May 14;125(19):5734-40. doi: 10.1021/ja0295218.
7
Epoxidation of linear, branched and cyclic alkenes catalyzed by unspecific peroxygenase.非特异性过氧化物酶催化的直链、支链和环状烯烃环氧化。
Enzyme Microb Technol. 2013 May 10;52(6-7):370-6. doi: 10.1016/j.enzmictec.2013.02.013. Epub 2013 Mar 6.
8
First success of catalytic epoxidation of olefins by an electron-rich iron(III) porphyrin complex and H2O2: imidazole effect on the activation of H2O2 by iron porphyrin complexes in aprotic solvent.富电子铁（III）卟啉配合物与过氧化氢实现烯烃催化环氧化的首次成功：咪唑在非质子溶剂中对铁卟啉配合物活化过氧化氢的影响
J Inorg Biochem. 2000 Jul 1;80(3-4):219-25. doi: 10.1016/s0162-0134(00)00085-4.
9
Aerobic methylcyclohexane-promoted epoxidation of stilbene over gold nanoparticles supported on Gd-doped titania.金纳米粒子负载于掺钆二氧化钛上促进的甲基环己烷有氧苯乙烯环氧化反应。
Dalton Trans. 2010 Sep 28;39(36):8457-63. doi: 10.1039/c0dt00350f. Epub 2010 Jul 7.
10
Terminal and internal olefin epoxidation with cobalt(II) as the catalyst: evidence for an active oxidant Co(II)-acylperoxo species.钴（II）作为催化剂的末端和内部烯烃环氧化：活性氧化剂 Co(II)-酰基过氧物种的证据。
J Org Chem. 2012 Sep 7;77(17):7307-12. doi: 10.1021/jo3009963. Epub 2012 Aug 22.

引用本文的文献

1
Research Progress in Epoxidation of Light Small-Molecule Olefins.轻质小分子烯烃环氧化反应的研究进展
Molecules. 2025 Mar 17;30(6):1340. doi: 10.3390/molecules30061340.
2
Rational Design of Self-Supported CuO -Decorated Composite Films as an Efficient and Easy-Recycling Catalyst for Styrene Oxidation.自支撑氧化铜修饰复合薄膜作为苯乙烯氧化高效且易于回收催化剂的合理设计
ACS Omega. 2021 Jul 6;6(28):18157-18168. doi: 10.1021/acsomega.1c02031. eCollection 2021 Jul 20.
3
A new and efficient methodology for olefin epoxidation catalyzed by supported cobalt nanoparticles.

本文引用的文献

1
Highly efficient CuCr-MMO catalyst for a base-free styrene epoxidation with HO as the oxidant: synergistic effect between Cu and Cr.高效 CuCr-MMO 催化剂用于以 HO 为氧化剂的无碱苯乙烯环氧化反应：Cu 和 Cr 之间的协同作用。
Dalton Trans. 2019 Nov 21;48(43):16402-16411. doi: 10.1039/c9dt02357g. Epub 2019 Oct 23.
2
Strategies for UHPLC-MS/MS-Based Analysis of Different Classes of Acyl Chain Oxidation Products Resulting from Thermo-Oxidation of Sitostanyl Oleate.基于 UHPLC-MS/MS 的不同类型酰基链氧化产物分析策略，这些产物是由甾醇油酸酯的热氧化产生的。
J Agric Food Chem. 2019 Oct 30;67(43):12072-12083. doi: 10.1021/acs.jafc.9b05197. Epub 2019 Oct 16.
3
一种由负载型钴纳米颗粒催化的烯烃环氧化新的高效方法。
Beilstein J Org Chem. 2021 Feb 22;17:519-526. doi: 10.3762/bjoc.17.46. eCollection 2021.
Regioisomer-independent quantification of fatty acid oxidation products by HPLC-ESI-MS/MS analysis of sodium adducts.
通过高效液相色谱-电喷雾串联质谱分析钠离子加合物对脂肪酸氧化产物进行区域异构体非依赖性定量。
Sci Rep. 2019 Aug 1;9(1):11197. doi: 10.1038/s41598-019-47693-5.
4
Bioinspired Manganese and Iron Complexes for Enantioselective Oxidation Reactions: Ligand Design, Catalytic Activity, and Beyond.仿生锰和铁配合物用于对映选择性氧化反应：配体设计、催化活性及其他。
Acc Chem Res. 2019 Aug 20;52(8):2370-2381. doi: 10.1021/acs.accounts.9b00285. Epub 2019 Jul 23.
5
Characterization and Reactivity of a Tetrahedral Copper(II) Alkylperoxido Complex.四面体铜（II）烷基过氧配合物的表征与反应活性
Chemistry. 2019 Aug 22;25(47):11157-11165. doi: 10.1002/chem.201902669. Epub 2019 Aug 1.
6
Visible-Light-Promoted Ring-Opening Alkynylation, Alkenylation, and Allylation of Cyclic Hemiacetals through β-Scission of Alkoxy Radicals.可见光促进的环状半缩醛通过烷氧基自由基的β-断裂进行的开环炔基化、烯基化和烯丙基化反应。
Chemistry. 2019 Jul 5;25(38):8992-8995. doi: 10.1002/chem.201901762. Epub 2019 Jun 6.
7
Sequential Intercellular Delivery Nanosystem for Enhancing ROS-Induced Antitumor Therapy.序贯细胞内递药纳米系统增强 ROS 诱导的抗肿瘤治疗。
Nano Lett. 2019 Jun 12;19(6):3505-3518. doi: 10.1021/acs.nanolett.9b00336. Epub 2019 May 2.
8
Wettability Control of Co-SiO@Ti-Si Core-Shell Catalyst to Enhance the Oxidation Activity with the In Situ Generated Hydroperoxide.通过原位生成氢过氧化物来控制Co-SiO@Ti-Si核壳催化剂的润湿性以增强氧化活性
ACS Appl Mater Interfaces. 2019 Apr 24;11(16):14702-14712. doi: 10.1021/acsami.8b19704. Epub 2019 Apr 15.
9
(Salen)Mn(iii)-catalyzed chemoselective acylazidation of olefins.（Salen）锰（Ⅲ）催化烯烃的化学选择性酰基叠氮化反应。
Chem Sci. 2018 Jun 19;9(28):6085-6090. doi: 10.1039/c8sc01882k. eCollection 2018 Jul 28.
10
Non-Heme Iron Catalysts for Olefin Epoxidation: Conformationally Rigid Aryl-Aryl Junction To Support Amine/Imine Multidentate Ligands.非血红素铁催化剂用于烯烃环氧化：刚性的芳基-芳基连接基支持胺/亚胺多齿配体。
Chemistry. 2018 Jun 18;24(34):8632-8638. doi: 10.1002/chem.201800447. Epub 2018 May 22.