一种通过串联反应从醌式体系生成的高度取代的吡嗪并环烷。
A highly substituted pyrazinophane generated from a quinoidal system via a cascade reaction.
作者信息
Anderson Christopher L, Liang Jiatao, Teat Simon J, Garzón-Ruiz Andrés, Nenon David P, Navarro Amparo, Liu Yi
机构信息
The Molecular Foundry, Lawrence Berkeley National Laboratory, One Cyclotron Road, Berkeley, California 94720, USA.
出版信息
Chem Commun (Camb). 2020 Apr 25;56(32):4472-4475. doi: 10.1039/d0cc00916d. Epub 2020 Mar 23.
The generation of a highly-substituted 2.2pyrazinophane via a cascade reaction is presented. The pyrazinophane product is formed via the dimerization of a member of the para-azaquinodimethane (p-AQM) family of conjugated quinoidal compounds-reactivity that sheds light on the nature of stability in p-AQMs. Additionally, the electronic and structural nature of this highly-strained ring system are characterized.
本文介绍了通过串联反应生成高度取代的2.2吡嗪并环戊烷的过程。吡嗪并环戊烷产物是通过对-氮杂醌二甲烷（p-AQM）共轭醌类化合物家族中的一个成员进行二聚反应形成的，这种反应活性揭示了p-AQMs的稳定性本质。此外，还对这个高度张力环系统的电子和结构性质进行了表征。
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