Anderson Christopher L, Liang Jiatao, Teat Simon J, Garzón-Ruiz Andrés, Nenon David P, Navarro Amparo, Liu Yi
The Molecular Foundry, Lawrence Berkeley National Laboratory, One Cyclotron Road, Berkeley, California 94720, USA.
Chem Commun (Camb). 2020 Apr 25;56(32):4472-4475. doi: 10.1039/d0cc00916d. Epub 2020 Mar 23.
The generation of a highly-substituted 2.2pyrazinophane via a cascade reaction is presented. The pyrazinophane product is formed via the dimerization of a member of the para-azaquinodimethane (p-AQM) family of conjugated quinoidal compounds-reactivity that sheds light on the nature of stability in p-AQMs. Additionally, the electronic and structural nature of this highly-strained ring system are characterized.
本文介绍了通过串联反应生成高度取代的2.2吡嗪并环戊烷的过程。吡嗪并环戊烷产物是通过对-氮杂醌二甲烷（p-AQM）共轭醌类化合物家族中的一个成员进行二聚反应形成的，这种反应活性揭示了p-AQMs的稳定性本质。此外，还对这个高度张力环系统的电子和结构性质进行了表征。
