Song Shaofei, Zhou Hang, Hicks Garion, Rastogi Chandresh Kumar, Yu Qing, Manners Ian, Winnik Mitchell A
Department of Chemistry, University of Toronto, Toronto, Ontario M5S 3H6, Canada.
Chem Commun (Camb). 2020 Apr 28;56(33):4595-4598. doi: 10.1039/d0cc00153h. Epub 2020 Mar 25.
This work presents a simple approach to access uniform fiber-like micelles by single-step crystalization-driven co-self-assembly of a polyferrocenyldimethylsilane (PFS) block copolymer with a trace of a PFS homopolymer. The length of micelles in the μm range could be controlled by changing the amount of homopolymer in the mixture.
这项工作提出了一种简单的方法,通过聚二茂铁基二甲基硅烷(PFS)嵌段共聚物与痕量PFS均聚物的一步结晶驱动共自组装来获得均匀的纤维状胶束。通过改变混合物中均聚物的量,可以控制μm范围内胶束的长度。