Zhang Jing, Lai Rong-Da, Wu Yan-Lan, Zhu Zeng-Kui, Sun Yan-Qiong, Zeng Qing-Xin, Li Xin-Xiong, Zheng Shou-Tian
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, P. R. China.
State Key Laboratory of Structural chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, P. R. China.
Chem Asian J. 2020 May 15;15(10):1574-1579. doi: 10.1002/asia.202000294. Epub 2020 Apr 9.
In this work, two rare high-dimensional polyoxoniobates with formulas of H [Cu(en)(H O) ][Cu(en) ] [Dy(H O) ] [Nb -O (H O) ] ⋅ 36H O (1) and H K[Cu(en) (H O)] [Cu(en) ] -[Eu(H O) ] [Nb O (H O) ] ⋅ 2en ⋅ 45H O (2) have been obtained under hydrothermal conditions. These extended materials are constructed from lanthanide-incorporated triangular-prism-like polyoxoniobate secondary building units (SBUs) {[Ln(H O) ] [Nb O (H O) ] } (Ln=Dy, Eu). 1 and 2 represent the first examples of high-dimensional polyoxometalate materials based on such lanthanide-incorporated triangular-prism-like polyoxoniobate SBUs. Furthermore, the proton conduction property and the luminescent emission of these materials were evaluated.
在本工作中，通过水热条件获得了两种罕见的高维聚氧铌酸盐，其化学式分别为H [Cu(en)(H₂O)₂][Cu(en)₂]₂[Dy(H₂O)₆][Nb₉O₂₈(H₂O)₄] ⋅ 36H₂O (1)和H₉K[Cu(en)₂(H₂O)₂]₂[Cu(en)₂]₂[Eu(H₂O)₆][Nb₉O₂₈(H₂O)₄] ⋅ 2en ⋅ 45H₂O (2)。这些扩展材料由掺入镧系元素的三棱柱状聚氧铌酸二级结构单元（SBUs）{[Ln(H₂O)₆][Nb₉O₂₈(H₂O)₄]}（Ln = Dy, Eu）构建而成。1和2代表了基于此类掺入镧系元素的三棱柱状聚氧铌酸SBUs的高维多金属氧酸盐材料的首个实例。此外，还评估了这些材料的质子传导性能和发光发射特性。
