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星际云中的前生物化学与类生物分子的形成和原行星盘中的类生物分子的形成。

Prebiotic Astrochemistry and the Formation of Molecules of Astrobiological Interest in Interstellar Clouds and Protostellar Disks.

机构信息

NASA Ames Research Center, MS 245-6, Moffett Field, California 94035, United States.

BAER Institute, NASA Research Park, MS 18-4, Moffett Field, California 94035, United States.

出版信息

Chem Rev. 2020 Jun 10;120(11):4616-4659. doi: 10.1021/acs.chemrev.9b00560. Epub 2020 Mar 31.

Abstract

Despite the generally hostile nature of the environments involved, chemistry does occur in space. Molecules are seen in environments that span a wide range of physical and chemical conditions and that clearly were created by a multitude of chemical processes, many of which differ substantially from those associated with traditional equilibrium chemistry. The wide range of environmental conditions and processes involved with chemistry in space yields complex populations of materials, and because the elements H, C, O, and N are among the most abundant in the universe, many of these are organic in nature, including some of direct astrobiological interest. Much of this chemistry occurs in "dense" interstellar clouds and protostellar disks surrounding forming stars because these environments have higher relative densities and more benign radiation fields than in stellar ejectae or the diffuse interstellar medium. Because these are the environments in which new planetary systems form, some of the chemical species made in these environments are expected to be delivered to the surfaces of planets where they can potentially play key roles in the origin of life. Because these chemical processes are universal and should occur in these environments wherever they are found, this implies that some of the starting materials for life are likely to be widely distributed throughout the universe.

摘要

尽管所涉及的环境通常具有敌意,但化学确实存在于太空中。在跨越广泛物理和化学条件的环境中观察到分子,这些环境显然是由多种化学过程产生的,其中许多过程与传统的平衡化学有很大的不同。太空中化学涉及的广泛环境条件和过程产生了复杂的物质群体,由于 H、C、O 和 N 等元素是宇宙中最丰富的元素之一,因此其中许多物质具有有机性质,其中一些具有直接的天体生物学意义。由于这些环境的相对密度较高,辐射场也较温和,因此许多这样的化学物质存在于“密集”的星际云团和围绕形成恒星的原行星盘中,而不是在恒星喷出物或弥漫的星际介质中。由于这些是新行星系统形成的环境,因此预计在这些环境中制造的一些化学物质将被输送到行星表面,在那里它们可能在生命起源中发挥关键作用。由于这些化学过程是普遍存在的,并且应该在它们被发现的任何地方的这些环境中发生,这意味着生命的一些起始材料可能在整个宇宙中广泛分布。

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