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由苄基醚自缩合化合物和外部交联剂制备超交联聚合物的设计

The design of hypercrosslinked polymers from benzyl ether self-condensing compounds and external crosslinkers.

作者信息

Woodward Robert T

机构信息

Department of Chemical Engineering, Imperial College London, South Kensington Campus, SW7 2AZ London, UK.

出版信息

Chem Commun (Camb). 2020 May 5;56(36):4938-4941. doi: 10.1039/d0cc01002b.

Abstract

Hypercrosslinked polymers were produced via the self-condensation of benzyl ether compounds, providing a one-component route to highly porous networks and significant reductions in catalyst waste compared to conventional routes. These compounds also represent a new class of external crosslinkers, able to impart improved textural properties when compared to standard aliphatic crosslinkers.

摘要

通过苄基醚化合物的自缩合制备了超交联聚合物,与传统方法相比,这提供了一种制备高孔隙率网络的单组分方法,并显著减少了催化剂废料。与标准脂肪族交联剂相比,这些化合物还代表了一类新型的外部交联剂,能够赋予更好的织构性质。

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