Efficient recovery of Cu(II) by LTA-zeolites with hierarchical pores and their resource utilization in electrochemical denitrification: Environmentally friendly design and reutilization of waste in water.

Water pollution seriously endangers human health and the environment. Here we prepared and tested mesoporous LTA zeolites for the adsorption of Cu(II) from aqueous media and the captured copper was further used for electrochemical nitrate reduction. The prepared hierarchically porous LTA exhibited a high capacity (341.5 mg g) for Cu(II) adsorption, following the pseudo-second-order kinetic and Freundlich adsorption isotherm models well. The Cu-LTA sample was characterised by various analytical methods, and Cu(I) species were identified as the active sites for nitrate electrochemical reduction. Based on the spectral characterization and reducibility, strong metal-support interaction was found between copper and LTA, which is beneficial to the dispersion of active sites and their contacts with nitrates. In total, 10.1 g-N-NO g-Cu was reduced over the Cu-LTA-modified cathode in a three-electrode system with high N selectivity (92.1 %). Compared to purely microporous zeolites, mesoporous LTA has a higher capacity for Cu(II) removal and nitrate reduction. The mesoporous structure allows easy access to the inner active sites with low diffusion resistance. The low Tafel slope and high current density confirm the high activity of the mesoporous Cu-LTA, making it a promising and efficient material for the removal and reuse of heavy metal ions.