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通过扭转诱导的相到相热和分子迁移率增强再生碳复合材料系统的混合和热管理。

Enhancing Mixing and Thermal Management of Recycled Carbon Composite Systems by Torsion-Induced Phase-to-Phase Thermal and Molecular Mobility.

作者信息

Jian Ranran, Shi Zhonghe, Liu Haichao, Yang Weimin, Sain Mohini

机构信息

College of Electromechanical Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong Province, China.

Centre for Biocomposites and Biomaterial Processing, Department of Mechanical and Industrial Engineering, University of Toronto, Toronto, ON M5S 3B3, Canada.

出版信息

Polymers (Basel). 2020 Apr 1;12(4):771. doi: 10.3390/polym12040771.

Abstract

A novel torsion screw has been proposed to resolve the inadequate control of mass transfer and the thermal management of two component polymer blends and their carbon fiber composites. The novel torsional screw distinctly introduced radial flow in the torsion screw channel, which is a significant improvement over the flow pattern developed by the conventional screw. The heat transfer and mixing behavior of melt mixtures are enhanced by adapting screws with torsion elements compared with the traditional screw elements. Heat transfer efficacy in the polypropylene-polystyrene bi-phasic extrusion process improved with the increase in torsion element numbers. An increased number of newly designed torsional elements also improved the dispersion of minor phase in bi-phase polypropylene-polystyrene composition and their carbon fiber composites. The unique flow pattern induced by the torsion elements shows a synergistic effect on the melt-phase mass flow and the thermal flow field facilitating phase-to-phase thermal and molecular mobility and enhanced fiber orientation, crystallinity and mechanical properties of composite made from recycled carbon fiber/polypropylene. Microtomographs of recycled carbon fiber demonstrated the extraordinary ability of a torsion screw element to orient carbon fiber in both axial and radial directions.

摘要

一种新型扭转螺杆已被提出,以解决两组分聚合物共混物及其碳纤维复合材料在传质控制不足和热管理方面的问题。这种新型扭转螺杆在扭转螺杆通道中明显引入了径向流,这是对传统螺杆所形成流型的显著改进。与传统螺杆元件相比,采用带有扭转元件的螺杆可增强熔体混合物的传热和混合行为。在聚丙烯-聚苯乙烯双相挤出过程中,传热效率随着扭转元件数量的增加而提高。新设计的扭转元件数量增加也改善了次要相在双相聚丙烯-聚苯乙烯组合物及其碳纤维复合材料中的分散。扭转元件所诱导的独特流型对熔体相质量流和热流场具有协同作用,促进了相间的热和分子迁移,并增强了由回收碳纤维/聚丙烯制成的复合材料的纤维取向、结晶度和机械性能。回收碳纤维的显微断层扫描显示了扭转螺杆元件在轴向和径向上使碳纤维取向的非凡能力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/03d7/7240696/9d1bcd916724/polymers-12-00771-g001.jpg

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