用于全聚合物太阳能电池的苝酰亚胺基共轭聚合物。

Perylene Diimide-Based Conjugated Polymers for All-Polymer Solar Cells.

作者信息

Shi Qinqin, Wu Jianfei, Wu Xiaoxi, Peng Aidong, Huang Hui

机构信息

College of Materials Science and Opto-Electronic Technology &, Center of Materials Science and Optoelectronics Engineering &, CAS Center for Excellence in Topological Quantum Computation &, CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.

出版信息

Chemistry. 2020 Oct 1;26(55):12510-12522. doi: 10.1002/chem.202001011. Epub 2020 Aug 11.

DOI:10.1002/chem.202001011

PMID:32246541

Abstract

In recent decades, non-fullerene acceptors (NFAs) are undergoing rapid development and emerging as a hot area in the field of organic solar cells. Among the high-performance non-fullerene acceptors, aromatic diimide-based electron acceptors remain to be highly promising systems. This review discusses the important progress of perylene diimide (PDI)-based polymers as non-fullerene acceptors in all-polymer solar cells (all-PSCs) since 2014. The relationship between structure and property, matching aspects between donors and acceptors, and device fabrications are unveiled from a synthetic chemist perspective.

摘要

近几十年来，非富勒烯受体（NFAs）正在迅速发展，并成为有机太阳能电池领域的一个热门领域。在高性能非富勒烯受体中，基于芳香二亚胺的电子受体仍然是非常有前景的体系。本文综述了自2014年以来基于苝二亚胺（PDI）的聚合物作为非富勒烯受体在全聚合物太阳能电池（all-PSC）中的重要进展。从合成化学家的角度揭示了结构与性能之间的关系、供体与受体之间的匹配方面以及器件制备。