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蔗渣纤维素负载纳米TiO光催化耦合微生物载体的制备及其光催化性能

Preparation and Photocatalytic Properties of a Bagasse Cellulose-Supported Nano-TiO Photocatalytic-Coupled Microbial Carrier.

作者信息

Xiong Jianhua, Liang Yinna, Cheng Hao, Guo Shuocheng, Jiao Chunlin, Zhu Hongxiang, Wang Shuangfei, Liang Jiaxiang, Yang Qifeng, Chen Guoning

机构信息

School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China.

Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning 530004, China.

出版信息

Materials (Basel). 2020 Apr 2;13(7):1645. doi: 10.3390/ma13071645.

Abstract

Intimate coupling of photocatalysis and biodegradation (ICPB) has shown promise in removing unwanted organic compounds from water. In this study, bagasse cellulose titanium dioxide composite carrier (SBC-TiO) was prepared by low-temperature foaming methods. The optimum preparation conditions, material characterization and photocatalytic performance of the composite carrier were then explored. By conducting a single factor test, we found that bagasse cellulose with a mass fraction of 4%, a polyvinyl alcohol solution (PVA) with a mass fraction of 5% and 20 g of a pore-forming agent were optimum conditions for the composite carrier. Under these conditions, good wet density, porosity, water absorption and retention could be realized. Scanning electron microscopy (SEM) results showed that the composite carrier exhibited good biologic adhesion. X-ray spectroscopy (EDS) results confirmed the successful incorporation of nano-TiO dioxide into the composite carrier. When the mass concentration of methylene blue (MB) was 10 mg L at 200 mL, 2 g of the composite carrier was added and the initial pH value of the reaction was maintained at 6, the catalytic effect was best under these conditions and the degradation rate reached 78.91% after 6 h. The method of preparing the composite carrier can aid in the degradation of hard-to-degrade organic compounds via ICPB. These results provide a solid platform for technical research and development in the field of wastewater treatment.

摘要

光催化与生物降解的紧密耦合(ICPB)在去除水中有害有机化合物方面已展现出前景。在本研究中,通过低温发泡法制备了甘蔗渣纤维素二氧化钛复合载体(SBC-TiO)。随后探究了该复合载体的最佳制备条件、材料表征及光催化性能。通过单因素试验发现,质量分数为4%的甘蔗渣纤维素、质量分数为5%的聚乙烯醇溶液(PVA)和20 g的造孔剂是复合载体的最佳条件。在此条件下,可实现良好的湿密度、孔隙率、吸水性和持水性。扫描电子显微镜(SEM)结果表明,复合载体表现出良好的生物附着力。X射线能谱(EDS)结果证实纳米二氧化钛成功掺入复合载体中。当亚甲基蓝(MB)的质量浓度为10 mg/L、体积为200 mL时,加入2 g复合载体并将反应初始pH值维持在6,在此条件下催化效果最佳,6 h后降解率达到78.91%。制备复合载体的方法有助于通过ICPB降解难降解有机化合物。这些结果为废水处理领域的技术研发提供了坚实的平台。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ef71/7178418/4e19bf801e1d/materials-13-01645-g001.jpg

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