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仿生功能材料的最新进展具有特定润湿性:从自然到超越自然。

Recent advances of bioinspired functional materials with specific wettability: from nature and beyond nature.

机构信息

State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, People's Republic of China.

出版信息

Nanoscale Horiz. 2019 Jan 1;4(1):52-76. doi: 10.1039/c8nh00223a. Epub 2018 Sep 18.

Abstract

Through 3.7 billion years of evolution and natural selection, plants and animals in nature have ingeniously fulfilled a broad range of fascinating functions to achieve optimized performance in responding and adapting to changes in the process of interacting with complex natural environments. It is clear that the hierarchically organized micro/nanostructures of the surfaces of living organisms decisively manage fascinating and amazing functions, regardless of the chemical components of their building blocks. This conclusion now allows us to elucidate the underlying mechanisms whereby these hierarchical structures have a great impact on the properties of the bulk material. In this review, we mainly focus on advances over the last three years in bioinspired multiscale functional materials with specific wettability. Starting from selected naturally occurring surfaces, manmade bioinspired surfaces with specific wettability are introduced, with an emphasis on the cooperation between structural characteristics and macroscopic properties, including lotus leaf-inspired superhydrophobic surfaces, fish scale-inspired superhydrophilic/underwater superoleophobic surfaces, springtail-inspired superoleophobic surfaces, and Nepenthes (pitcher plant)-inspired slippery liquid-infused porous surfaces (SLIPSs), as well as other multifunctional surfaces that combine specific wettability with mechanical properties, optical properties and the unidirectional transport of liquid droplets. Afterwards, various top-down and bottom-up fabrication techniques are presented, as well as emerging cutting-edge applications. Finally, our personal perspectives and conclusions with regard to the transfer of micro- and nanostructures to engineered materials are provided.

摘要

通过 37 亿年的进化和自然选择,自然界中的动植物巧妙地实现了广泛的迷人功能,以在与复杂自然环境相互作用的过程中优化响应和适应变化的能力。显然,无论其构建块的化学成分如何,生物体表面的分层微/纳米结构都决定了迷人而惊人的功能。这一结论现在使我们能够阐明这些分层结构对大块材料性能有重大影响的潜在机制。在这篇综述中,我们主要关注过去三年中具有特定润湿性的仿生多尺度功能材料的进展。从选定的天然存在的表面开始,引入了具有特定润湿性的人造仿生表面,重点介绍了结构特征与宏观性能之间的协同作用,包括荷叶启发的超疏水表面、鱼鳞启发的超亲水/水下超疏油表面、弹尾虫启发的超疏油表面以及猪笼草(瓶状植物)启发的滑液注入多孔表面(SLIPS)以及其他将特定润湿性与机械性能、光学性能和液滴单向传输相结合的多功能表面。之后,介绍了各种自上而下和自下而上的制造技术以及新兴的前沿应用。最后,我们对微纳结构向工程材料的转移提出了个人的观点和结论。

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