吖啶橙作为三（2,2'-联吡啶）钌（ii）电致化学发光的有效共反应物及其在硫脲选择性和灵敏检测中的应用。
Acridine orange as a coreactant for efficient electrogenerated chemiluminescence of tris(2,2'-bipyridine)ruthenium(ii) and its use in selective and sensitive detection of thiourea.
机构信息
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China.
出版信息
Chem Commun (Camb). 2020 May 11;56(38):5154-5157. doi: 10.1039/d0cc01273d. Epub 2020 Apr 7.
A new and efficient anodic Ru(bpy) ECL system by using acridine orange (3,6-Bis(dimethylamino)acridine, AO) as a coreactant was reported in a neutral medium. The developed Ru(bpy)-AO system displayed a higher ECL intensity than that of the classic Ru(bpy)- oxalate ECL system, and was further exploited for the ECL detection of thiourea for the first time.
本文报道了一种在中性介质中，以吖啶橙（3,6-二甲基氨基吖啶，AO）为共反应物的新型高效阳极 Ru(bpy) ECL 体系。与经典的 Ru(bpy)-草酸盐 ECL 体系相比，所开发的 Ru(bpy)-AO 体系显示出更高的 ECL 强度，并首次将其用于检测硫脲。
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