可见光下硫代酰胺无金属脱氢脱硫制备腈类化合物
Metal-free dehydrosulfurization of thioamides to nitriles under visible light.
作者信息
Xu Tianxiao, Cao Tianpeng, Feng Qingyuan, Huang Shenlin, Liao Saihu
机构信息
Key Laboratory of Molecule Synthesis and Function Discovery, College of Chemistry, Fuzhou University, 2 Xueyuan Road, Fuzhou 350116, P. R. China.
出版信息
Chem Commun (Camb). 2020 May 11;56(38):5151-5153. doi: 10.1039/d0cc01380c. Epub 2020 Apr 7.
PMID:32255113
Abstract
A visible light-mediated, metal-free dehydrosulfurization reaction of thioamides to nitriles is described. This reaction features high yields, mild reaction conditions, and the use of a cheap organic dye as the photoredox catalyst and air as the oxidant.
摘要
本文描述了一种可见光介导的、无金属的硫代酰胺脱水脱硫生成腈的反应。该反应具有产率高、反应条件温和的特点，并且使用廉价的有机染料作为光氧化还原催化剂，以空气作为氧化剂。
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