Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford St., Cambridge, MA 02138, USA.
Chem Commun (Camb). 2020 May 14;56(39):5247-5250. doi: 10.1039/c9cc09892e. Epub 2020 Apr 9.
Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb(v) bis-μ-oxo corrole that photochemically oxidises the C-H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-electron photoreaction.
磷属元素配合物是介导两电子步骤中多电子化学反应的理想选择。我们报告了一种 Sb(v) 双-μ-氧代卟啉，它可以光化学氧化有机底物的 C-H 键。在甲苯的情况下，底物被氧化为苯甲醛，这是四电子光反应的罕见实例。
