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基于聚合物纳米纤维支架的铜酞菁传感器传感性能的改进

Improvement of Sensing Properties for Copper Phthalocyanine Sensors Based on Polymer Nanofibers Scaffolds.

作者信息

Wang Lu, Wang Lijuan, Yang Guocheng, Xie Qiang, Zhong Sai, Su Xin, Hou Yuhang, Zhang Bo

机构信息

School of Chemical Engineering, Changchun University of Technology, Changchun 130012, P R China.

出版信息

Langmuir. 2020 Apr 28;36(16):4532-4539. doi: 10.1021/acs.langmuir.9b03636. Epub 2020 Apr 16.

Abstract

An effectual and understandable route for the fabrication techniques of stereoscopic NO sensor is provided in this work. As the gas-sensing layer of the sensor, copper phthalocyanine (CuPc) grew on the top of poly(vinyl alcohol) (PVA) nanofibers (NFs). The sensitivity of the CuPc/PVA NFs stereoscopic sensors to NO was over 829%/ppm, while the sensitivity of the continuous CuPc films sensors was 2 orders of magnitude lower than that of the stereoscopic ones. To the responsivities at 25 ppm of NO, the CuPc/PVA NFs stereoscopic sensors were about four times stronger than that of the continuous CuPc films sensors. For the recovery time, the CuPc/PVA NFs stereoscopic sensors were over eight times faster than the continuous CuPc films sensors. This general tactic can be used to prepare various toxic gas sensors to improve the overall performance of the devices.

摘要

本工作提供了一种有效且易懂的立体NO传感器制造技术路线。作为传感器的气敏层,铜酞菁(CuPc)生长在聚乙烯醇(PVA)纳米纤维(NFs)顶部。CuPc/PVA NFs立体传感器对NO的灵敏度超过829%/ppm,而连续CuPc薄膜传感器的灵敏度比立体传感器低2个数量级。对于25 ppm NO的响应率,CuPc/PVA NFs立体传感器比连续CuPc薄膜传感器强约四倍。在恢复时间方面,CuPc/PVA NFs立体传感器比连续CuPc薄膜传感器快八倍以上。这种通用策略可用于制备各种有毒气体传感器,以提高器件的整体性能。

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