Preparation and Gas-Sensing Properties of Two-Dimensional Molybdenum Disulfide/One-Dimensional Copper Phthalocyanine Heterojunction.

Although 2D MoS alone shows excellent gas-sensing performance, it is prone to stacking when used as the sensitive layer, resulting in insufficient contact with the target gas and lower sensitivity. To solve this, a 2D-MoS/1D-CuPc heterojunction was prepared with different weight ratios of MoS nanosheets to CuPc micro-nanowires, and its room-temperature gas-sensing properties were studied. The response of the 2D-MoS/1D-CuPc heterojunction to a target gas was related to the weight ratio of MoS to CuPc. When the weight ratio of MoS to CuPc was 20:7 (7-CM), the gas sensitivity of MoS/CuPc composites was the best. Compared with the pure MoS sensor, the responses of 7-CM to 1000 ppm formaldehyde (CHO), acetone (CHO), ethanol (CHO), and 98% RH increased by 122.7, 734.6, 1639.8, and 440.5, respectively. The response of the heterojunction toward CHO was twice that of CHO and 13 times that of CHO. In addition, the response time of all sensors was less than 60 s, and the recovery time was less than 10 s. These results provide an experimental reference for the development of high-performance MoS-based gas sensors.