School of Chemistry and Chemical Ehgineering, Lanzhou City University, Lanzhou 730070, PR China.
School of Chemical Engineering, Northwest Minzu University, Lanzhou 730030, PR China; Key Laboratory for Utility of Environment Friendly Composite and Biomass in Universities of Gansu Province, Lanzhou 730030, PR China.
Ultrason Sonochem. 2020 Oct;67:105107. doi: 10.1016/j.ultsonch.2020.105107. Epub 2020 Mar 28.
With the rapid development of oil hydrogenation industry, the development of oil hydrogenation catalyst has also become a research hotspot. In this paper, ultrasound-assisted precipitation technique is used to prepare Ni/AlO catalyst. The effect of ultrasonic output power on catalyst performance is investigated. The prepared catalyst is applied to the hydrogenation reaction of castor oil. It is found that the prepared catalyst shows the best hydrogenation performance when ultrasonic output power, frequency and ultrasonic treatment time are 80 W, 40 kHz and 600 min respectively. It also indicates that ultrasound-assisted precipitation technique can reduce the particle size and increase the specific surface area of Ni/AlO catalyst so that its activity is improved. In addition, six important elements that should be considered in the development of industrial oil refining catalysts are discussed, and the effects of these factors on the catalyst performance are discussed. Finally, new way for improving catalyst performance is given, and the application of some new materials and methods in oil refining is introduced.
随着石油加氢工业的快速发展,石油加氢催化剂的开发也成为研究热点。本文采用超声辅助沉淀法制备 Ni/AlO 催化剂,考察了超声输出功率对催化剂性能的影响。将制备的催化剂应用于蓖麻油加氢反应,发现当超声输出功率、频率和超声处理时间分别为 80W、40kHz 和 600min 时,催化剂表现出最佳的加氢性能。这也表明超声辅助沉淀法可以减小 Ni/AlO 催化剂的粒径,增加其比表面积,从而提高其活性。此外,还讨论了工业炼油催化剂开发中应考虑的六个重要因素,并讨论了这些因素对催化剂性能的影响。最后,给出了提高催化剂性能的新途径,并介绍了一些新材料和方法在炼油中的应用。