Graduate School of Life and Environmental Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305 8572, Japan.
Graduate School of Life and Environmental Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305 8572, Japan.
Bioresour Technol. 2020 Jul;308:123293. doi: 10.1016/j.biortech.2020.123293. Epub 2020 Apr 5.
In this study, in-situ biogas upgrading was examined and compared in lab-scale semi-continuous anaerobic digestion (AD) systems coupled with biogas recirculation under neutral and slightly alkaline conditions. Results showed that neutral pH (~7.5) condition yielded 6-7% higher CH content and 52-53% less HS production, while slightly alkaline condition (pH ~8.0) achieved 14-15% higher CH content and 76-77% less HS production under biogas recirculation in comparison to the control (no biogas recirculation). Little effect was noticed on daily CH production rate at slightly alkaline condition under biogas recirculation. Endogenous free ammonia nitrogen-dissolved inorganic carbon-volatile fatty acids (FAN-DIC-VFAs) buffer system was found to regulate the pH and alkalinity in the bulk liquor. Therefore, biogas recirculation under slightly alkaline condition is proposed as an efficient and sustainable strategy for biogas upgrading during AD of sewage sludge.
在这项研究中,在实验室规模的半连续厌氧消化(AD)系统中检查并比较了原位沼气升级,并在中性和略碱性条件下进行沼气再循环。结果表明,中性 pH(7.5)条件下 CH 含量高 6-7%,HS 产量低 52-53%,而在沼气再循环下,略碱性条件(pH8.0)下 CH 含量高 14-15%,HS 产量低 76-77%与对照(无沼气再循环)相比。在沼气再循环下,略碱性条件对每日 CH 产量的影响很小。发现内源性游离氨氮-溶解无机碳-挥发性脂肪酸(FAN-DIC-VFAs)缓冲系统可以调节主体液中的 pH 值和碱度。因此,建议在 AD 污水污泥过程中,在略碱性条件下进行沼气再循环,作为沼气升级的有效和可持续策略。