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通过1,3-双（硅氧基）-1,3-丁二烯与2-芳基磺酰基-3-乙氧基-2-烯-1-酮的区域选择性[3+3]环缩合首次合成4-（芳基磺酰基）苯酚。

First synthesis of 4-(arylsulfonyl)phenols by regioselective [3+3] cyclocondensations of 1,3-bis(silyloxy)-1,3-butadienes with 2-arylsulfonyl-3-ethoxy-2-en-1-ones.

作者信息

Riahi Abdolmajid, Shkoor Mohanad, Fatunsin Olumide, Lubbe Mathias, Reinke Helmut, Langer Peter

机构信息

Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany.

Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany.

出版信息

Tetrahedron Lett. 2009 Jan 7;50(1):115-117. doi: 10.1016/j.tetlet.2008.10.097. Epub 2008 Nov 1.

DOI:10.1016/j.tetlet.2008.10.097
PMID:32287440
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7111812/
Abstract

The formal [3+3] cyclization of 1,3-bis(silyloxy)-1,3-butadienes with readily available 2-arylsulfonyl-3-ethoxy-2-en-1-ones resulted in regioselective formation of 4-(arylsulfonyl)phenols.

摘要

1,3-双（硅氧基）-1,3-丁二烯与易于获得的2-芳基磺酰基-3-乙氧基-2-烯-1-酮进行形式上的[3+3]环化反应，区域选择性地生成了4-（芳基磺酰基）苯酚。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/9d27c9c1c7c0/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/569dcebae455/fx1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/0fe1574c8b85/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/900341b7936d/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/4ba8f92d1ed2/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/9d27c9c1c7c0/gr1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/569dcebae455/fx1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/0fe1574c8b85/gr2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/900341b7936d/gr3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/4ba8f92d1ed2/gr4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/46ab/7111812/9d27c9c1c7c0/gr1.jpg

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