配位聚合物中所含硼氢化物对二氧化碳的反应活性。
Reactivity of borohydride incorporated in coordination polymers toward carbon dioxide.
作者信息
Kadota Kentaro, Sivaniah Easan, Horike Satoshi
机构信息
Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
出版信息
Chem Commun (Camb). 2020 May 11;56(38):5111-5114. doi: 10.1039/d0cc01753a. Epub 2020 Apr 14.
PMID:32292964
Abstract
Borohydride (BH)-containing coordination polymers converted CO into HCO or [BH(OCHO)], whose reaction routes were affected by the electronegativity of metal ions and the coordination mode of BH. The reactions were investigated using thermal gravimetric analysis under CO gas flow, infrared spectroscopy, and NMR experiments.
摘要
含硼氢化物（BH）的配位聚合物将CO转化为HCO或[BH(OCHO)]，其反应路径受金属离子的电负性和BH的配位模式影响。采用热重分析、红外光谱和核磁共振实验在CO气流下对这些反应进行了研究。
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