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硫族汞化物纳米片-量子点异质结构作为一类新型的可连续调谐的明亮短波红外发射器。

Mercury Chalcogenide Nanoplatelet-Quantum Dot Heterostructures as a New Class of Continuously Tunable Bright Shortwave Infrared Emitters.

作者信息

Tenney Stephanie M, Vilchez Victoria, Sonnleitner Mikayla L, Huang Chengye, Friedman Hannah C, Shin Ashley J, Atallah Timothy L, Deshmukh Arundhati P, Ithurria Sandrine, Caram Justin R

机构信息

Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Drive, Los Angeles, California 90095-1569, United States.

Laboratoire de Physique et d'Étude des Matériaux, PSL Research University, CNRS UMR 8213, ESPCI ParisTech, 10 rue Vauquelin, 75005 Paris, France.

出版信息

J Phys Chem Lett. 2020 May 7;11(9):3473-3480. doi: 10.1021/acs.jpclett.0c00958. Epub 2020 Apr 21.

Abstract

Despite broad applications in imaging, energy conversion, and telecommunications, few nanoscale moieties emit light efficiently in the shortwave infrared (SWIR, 1000-2000 nm or 1.24-0.62 eV). We report quantum-confined mercury chalcogenide (HgX, where X = Se or Te) nanoplatelets (NPLs) can be induced to emit bright (QY > 30%) and tunable (900-1500+ nm) infrared emission from attached quantum dot (QD) "defect" states. We demonstrate near unity energy transfer from NPL to these QDs, which completely quench NPL emission and emit with a high QY through the SWIR. This QD defect emission is kinetically tunable, enabling controlled midgap emission from NPLs. Spectrally resolved photoluminescence demonstrates energy-dependent lifetimes, with radiative rates 10-20 times faster than those of their PbX analogues in the same spectral window. Coupled with their high quantum yield, midgap emission HgX dots on HgX NPLs provide a potential platform for novel optoelectronics in the SWIR.

摘要

尽管在成像、能量转换和电信领域有广泛应用,但很少有纳米级部分能在短波红外(SWIR,1000 - 2000纳米或1.24 - 0.62电子伏特)波段高效发光。我们报道了量子限域硫族汞化物(HgX,其中X = Se或Te)纳米片(NPL)可被诱导从附着的量子点(QD)“缺陷”态发出明亮(量子产率>30%)且可调谐(900 - 1500 +纳米)的红外光。我们证明了从NPL到这些量子点的近乎完全的能量转移,这完全淬灭了NPL的发光,并通过SWIR以高量子产率发光。这种量子点缺陷发光在动力学上是可调谐的,能够实现对NPL中间能隙发光的控制。光谱分辨光致发光表明其寿命与能量相关,辐射速率比相同光谱窗口中其PbX类似物快10 - 20倍。结合其高量子产率,HgX NPL上的中间能隙发光HgX量子点为SWIR中的新型光电子学提供了一个潜在平台。

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