Samonova Оlga A, Aseyeva Elena N, Chernitsova Olga V
Independent researcher.
Lomonosov Moscow State University, Faculty of Geography, GSP-1, Leninskie Gory, 119991, Moscow, Russia.
Data Brief. 2020 Mar 18;30:105450. doi: 10.1016/j.dib.2020.105450. eCollection 2020 Jun.
The pathways and behavior of rare earth elements (REEs) in the soil environment have been receiving greater significance due to their wide use in technological applications, agriculture, and medicine over the last two decades and insufficient information on their health effect and participation in soil and geochemical processes. In this paper, we report original data on rare earth elements in various particle size fractions separated from the topsoil horizons of two small erosional landforms located in an uncontaminated area of the central part of European Russia (the Middle Protva basin, the Kaluga region). Soil samples were collected from the top 10 cm along several soil transects. Soils were sampled at the landforms sides, bottoms, detrital fans and catchment areas considered as sources of solid matter. The sampling scheme used makes it possible to assess the REEs distribution from catchments to bottoms of the erosional landforms, as well as along their thalwegs. The collected bulk samples ( = 22) were physically fractionated and the concentrations of Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu were determined in five particle size fractions (1000-250, 250-50, 50-10, 10-1 and <1 µm, = 100) by ICP-MS using Elan-6100 spectrometer (Perkin Elmer Inc., USA). The data obtained also include the concentrations of Fe and Mn (ICP-AES), as well as the information on the total content of organic carbon (TOC), pH and particle size distribution of the bulk samples. The obtained dataset can be used for various purposes: it is suitable as a baseline for the assessment of pollution levels, exploring natural and anthropogenic anomalies, for revealing the association of REEs with specific particle size fractions and detecting the effect of parent material and lateral translocations of soil material and soil particles on the REEs levels.
在过去二十年中,稀土元素(REEs)在技术应用、农业和医学领域广泛使用,而关于其健康影响以及在土壤和地球化学过程中的参与情况的信息不足,因此土壤环境中稀土元素的迁移途径和行为受到了越来越多的关注。在本文中,我们报告了从位于俄罗斯欧洲部分中部未受污染地区(卡卢加州中普罗特瓦盆地)的两个小型侵蚀地貌的表土 horizons 中分离出的不同粒径级分中稀土元素的原始数据。沿着几条土壤样带从表层 10 厘米处采集土壤样本。在被视为固体物质来源的地貌侧面、底部、碎屑扇和集水区采集土壤样本。所采用的采样方案能够评估稀土元素从集水区到侵蚀地貌底部以及沿其谷底的分布情况。收集的 22 个散装样本进行了物理分级,并使用 Elan - 6100 光谱仪(美国珀金埃尔默公司)通过 ICP - MS 测定了五个粒径级分(1000 - 250、250 - 50、50 - 10、10 - 1 和 <1 µm,共 100 个)中 Sc、Y、La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb、Lu 的浓度。获得的数据还包括 Fe 和 Mn 的浓度(ICP - AES),以及散装样本的有机碳总含量(TOC)、pH 和粒径分布信息。所获得的数据集可用于各种目的:它适合作为评估污染水平、探索自然和人为异常、揭示稀土元素与特定粒径级分的关联以及检测母质和土壤物质及土壤颗粒的侧向迁移对稀土元素水平影响的基线。