Recycling of titanium-coagulated algae-rich sludge for enhanced photocatalytic oxidation of phenolic contaminants through oxygen vacancy.

In the 21st century, sludge disposal and resource recycling are global issues. Titanium coagulation has received increasing attention due its strong coagulation capability and sludge recycling. Titanium coagulation is highly efficient for the treatment of algae-laden micro-polluted surface water; however, the safe disposal of titanium-coagulated algae-rich sludge remains a challenge. Here, we report on the recycling of titanium-coagulated algae-rich sludge for the production of functional TiO nanoflowers (TNFs) through a simple hydrothermal and calcination process. Anatase TNFs (particle size of 10-15 nm) with petal-like structures (mesoporous), relatively high specific surface areas, i.e. 299.4 mg, and low band gaps, i.e. 2.67 eV (compared to P-25), were obtained. Additionally, oxygen vacancy (OV) was generated on the surface of the recycled TNFs based on electron paramagnetic resonance (EPR) results, which were verified by the first-principles calculations within density-functional theory. These TNFs display high photocatalytic performance for the degradation of diverse phenolic organic contaminants, such as bisphenol A, diphenyl phenol, p-tert-butyl phenol, and resorcinol, i.e. > 95%, under mild ultraviolet light irradiation and without any sacrificial reagents. Formation of OV on TNFs not only efficiently inhibited the recombination of photo-generated electrons and holes but also facilitated contaminant adsorption and photo-generated electron transfer on the surface of the recycled TNFs, thereby promoting the generation of holes and hydroxyl and superoxide radicals which were regarded as the reactive oxygen species for attacking contaminants in the reactions. This study proposes a new perspective on recycling chemical-coagulated sludge for producing functional nanomaterials as photocatalysts.