Jost Maximilian, Richter Roman-Malte, Balmer Markus, Peters Bertram, Dankert Fabian, von Hänisch Carsten
Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Straße, 35043 Marburg, Germany.
Dalton Trans. 2020 May 14;49(18):5787-5790. doi: 10.1039/d0dt01060j. Epub 2020 Apr 21.
The reaction of O(SiMeCl) with ammonia yielded the cyclic siloxazane O(SiMe)NH (1), which was used as a precursor for the synthesis of siloxazanide-type alkali metal salts. The metalation of 1 with the strong bases BzA (A = Na, K, Rb, Cs and Bz = benzyl) results in different dimensional structures depending on the alkali metal ion used. These results give new insights into framework design with inorganic building blocks and the coordination ability of siloxanes.
O(SiMeCl) 与氨反应生成了环状硅氧氮烷 O(SiMe)NH (1)，它被用作合成硅氧氮化物型碱金属盐的前体。1 与强碱 BzA（A = Na、K、Rb、Cs，Bz = 苄基）发生金属化反应，根据所使用的碱金属离子不同会产生不同维度的结构。这些结果为利用无机结构单元进行骨架设计以及硅氧烷的配位能力提供了新的见解。
