Michov B M
Department of Biochemistry, Academy of Medicine, Sofia, Bulgaria.
Electrophoresis. 1988 Apr;9(4):201-2. doi: 10.1002/elps.1150090410.
A quantitative theory of the Stern electric double layer is suggested. It is based on the view that every ion possesses a geometrical and an electrokinetic radius, that the ionic atmosphere begins from the geometrical one, and that the difference between these radii is the Stern quantity delta. The equations of the mentioned radii and the quantity delta are established and the values of the different potentials characterizing an ion and its ionic atmosphere are determined.
提出了一种斯特恩双电层的定量理论。该理论基于这样的观点:每个离子都有一个几何半径和一个电动半径,离子氛从几何半径处开始,且这两个半径之差就是斯特恩量δ。建立了上述半径和量δ的方程,并确定了表征离子及其离子氛的不同电位值。