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天然太阳辐射条件下催化剂TiO/FeO活性的实验数据。

Experimental data on activity catalyst TiO/FeO under natural solar radiation conditions.

作者信息

Castro-Sánchez A, Camargo-Amado R, Machuca-Martínez F

机构信息

Escuela de Ingeniería Química, Universidad del Valle, Calle 13 No. 100-00, Cali, Colombia.

出版信息

Data Brief. 2020 Apr 19;30:105490. doi: 10.1016/j.dib.2020.105490. eCollection 2020 Jun.

Abstract

In this document, the photocatalytic activity of TiO/FeO, prepared by the mixing of the pure oxides, was studied. The photocatalytic degradation of aqueous Methylene Blue (MB) solutions (10 and 30 ppm) was performed, the TiO/FeO catalysts in 80/20, 50/50 and 20/80 mass ratios were used during the test, artificial sunlight and natural solar radiation were tested at laboratory and pilot plant scale respectively. Besides, the kinetic reactions were evaluated according to the Langmuir-Hinshelwood model, the apparent velocity constants (k) were obtained for the TiO/FeO catalysts. In the laboratory test, the TiO/FeO catalyst (80/20) had a performance for 93.04% of discoloration, k = 0.0238 min, while for TiO/FeO (50/50, 20/80) had an 83.46%, 65.00% for discoloration of MB and the k values were 0.0154 min and 0.0098 min, respectively. In the solar test at pilot scale, the percentages of discoloration of 24.32%, and 57.78%, with k values of 0.00037 min, 0.00121 min respectively were obtained for TiO/FeO (80/20), a MB solution of 30 ppm, a load of 0.1 g/L and 0.3 g/L of the catalyst respectively.

摘要

在本文件中,研究了通过混合纯氧化物制备的TiO/FeO的光催化活性。进行了亚甲基蓝(MB)水溶液(10 ppm和30 ppm)的光催化降解实验,测试过程中使用了质量比为80/20、50/50和20/80的TiO/FeO催化剂,分别在实验室规模和中试规模下测试了人工阳光和自然太阳辐射。此外,根据朗缪尔 - 欣谢尔伍德模型评估了动力学反应,得到了TiO/FeO催化剂的表观速度常数(k)。在实验室测试中,TiO/FeO催化剂(80/20)的脱色率为93.04%,k = 0.0238 min,而TiO/FeO(50/50,20/80)对MB的脱色率分别为83.46%、65.00%,k值分别为0.0154 min和0.0098 min。在中试规模的太阳能测试中,对于TiO/FeO(80/20),分别使用0.1 g/L和0.3 g/L的催化剂,30 ppm的MB溶液,得到的脱色率分别为24.32%和57.78%,k值分别为0.00037 min和0.00121 min。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf9d/7182709/d40933857db0/gr1.jpg

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