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一种合成三核咪唑金（I）配合物的新方法及其银（I）诱导的光致发光行为。

A new approach to the synthesis of trinuclear gold(i) imidazolate complexes and their silver(i)-induced photoluminescence behavior.

作者信息

Ruiz Javier, Sol Daniel, Mateo María A, Vivanco Marilín, Badía-Laiño Rosana

机构信息

Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, 33006 Oviedo, Spain.

Departamento de Química Física y Analítica, Facultad de Química, Universidad de Oviedo, 33006 Oviedo, Spain.

出版信息

Dalton Trans. 2020 May 26;49(20):6561-6565. doi: 10.1039/d0dt01246g.

DOI:10.1039/d0dt01246g
PMID:32347262
Abstract

New trinuclear gold(i) N-arylimidazolate cluster complexes have been synthesized from cationic [Au(CNR)2]+ isocyanide complexes and their structure and photoluminescence behavior have been compared with those of their 1-methylimidazolate counterpart. A drastic change in their photophysical properties was observed upon coordination of the Ag+ cation.

摘要

新型三核金（I）N-芳基咪唑盐簇合物已由阳离子[Au(CNR)2]+异腈配合物合成，并且它们的结构和光致发光行为已与它们的1-甲基咪唑盐对应物进行了比较。在Ag+阳离子配位后，观察到它们的光物理性质发生了剧烈变化。

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