Recently, the multicolor fluorescent carbon dots (CDs) have drawn much attention due to their various applications. Herein, we report multicolor emissive CDs by solvent-controlled and solvent-responded approaches. The blue to red color emissive CDs are obtained by the solvothermal method by varying the solvent during the reaction. The red color emissive CDs (R-CDs) with good quantum yield is obtained in a water medium. The detailed characterization revealed that the solvent controls the particle size, band gap, and nitrogen doping concentration. Specifically, in the protic solvent, the high N content and presence of imine nitrogen are the reason for red emission. However, in an aprotic solvent, the least N doping and a lack of C-O groups are responsible for a blueshift. Interestingly, it was observed that the R-CDs provide a full range of visible color by dispersing in different immiscible solvents. The fluorescence emission in immiscible solvents is redshifted by enhancing the polarity. Moreover, the developed CDs detected the low water concentrations (≤0.2%, v/v) visually and fluorometrically in various organic solvents. Simultaneously, we have employed synthesized CDs in white-light-emitting diodes and fluorescent ink.