Wu Meixia, Zhou Xiang, Croft Mark, Ehrlich Steven, Khalid Syed, Wen Wen, Lapidus Saul H, Xu Xianghan, Li Man-Rong, Liu Zhongwu, Cheong Sang-Wook
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, PR China.
Rutgers Center for Emergent Materials and Department of Physics and Astronomy, Rutgers University, Piscataway, New Jersey 08854, United States.
Inorg Chem. 2020 May 18;59(10):6755-6762. doi: 10.1021/acs.inorgchem.9b03724. Epub 2020 May 4.
X-type hexaferrites have been receiving considerable attention due to their promising applications in many magnetic-electronic fields. However, the growth of single-crystal X-type hexaferrite is still a challenge. Herein we reported, for the first time, the preparation of single crystal X-type hexaferrite SrCoFeO (SrCoX) with high-quality and large size using floating-zone method with laser as the heating source. The crystals show rhombohedral symmetry with space group of -3 (No. 166, = 5.8935(1) Å and = 83.7438(17) Å). Co and Fe oxidation states were confirmed by the X-ray absorption near-edge spectroscopy. The prepared SrCoX exhibits a spin reorientation transition from easy-cone to easy-axis at of 343 K and a ferrimagnetism-paramagnetism transition at Curie temperature () of ∼743 K. The spin reorientation transition was accompanied by magnetocaloric effect (MCE). Both conventional and inverse MCEs were observed near with a magnetic field applied along the -axis. The maximum value of the magnetic entropy change along the -axis was evaluated to be 1.1 J/kg·K for a magnetic field change of 5 T.
