Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds.
作者信息
Yabune Natsuki, Nakajima Hiroshi, Nishioka Takanori
机构信息
Department of Chemistry, Graduate School of Science, Osaka City University, Osaka 558-8585, Japan.
出版信息
Dalton Trans. 2020 Jun 21;49(23):7680-7683. doi: 10.1039/d0dt01227k. Epub 2020 May 6.
PMID:32374316
Abstract
An N-heterocyclic carbene triplatinum complex with two triply bridging sulfide ligands reacts with a silver(i) salt and affords a heptanuclear complex. X-ray crystallographic analysis revealed that a silver(i) ion connects two triplatinum complexes with one of the three Pt-Pt bonds of each triplatinum unit.
摘要
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