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Metal-metal bond formation of triplatinum cores with a silver(i) ion affording a heptanuclear cluster bearing four Pt-Ag bonds.

作者信息

Yabune Natsuki, Nakajima Hiroshi, Nishioka Takanori

机构信息

Department of Chemistry, Graduate School of Science, Osaka City University, Osaka 558-8585, Japan.

出版信息

Dalton Trans. 2020 Jun 21;49(23):7680-7683. doi: 10.1039/d0dt01227k. Epub 2020 May 6.

DOI:10.1039/d0dt01227k
PMID:32374316
Abstract

An N-heterocyclic carbene triplatinum complex with two triply bridging sulfide ligands reacts with a silver(i) salt and affords a heptanuclear complex. X-ray crystallographic analysis revealed that a silver(i) ion connects two triplatinum complexes with one of the three Pt-Pt bonds of each triplatinum unit.

摘要

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引用本文的文献

1
Restriction of reaction sites on metal-sulfide cores induced by steric repulsion of bis-N-heterocyclic carbene ligands in trinuclear complexes bearing triply bridging sulfide ligands.在带有三桥联硫化物配体的三核配合物中，双-N-杂环卡宾配体的空间排斥作用对金属硫化物核上反应位点的限制。
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