Visible-Light-Mediated Manganese-Catalyzed Allylation Reactions of Unactivated Alkyl Iodides.
作者信息
Wang Xiaochen, Dong Jianyang, Li Yongqiang, Liu Yuxiu, Wang Qingmin
机构信息
State Key Laboratory of Elemento-Organic Chemistry, Research Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, People's Republic of China.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, People's Republic of China.
出版信息
J Org Chem. 2020 Jun 5;85(11):7459-7467. doi: 10.1021/acs.joc.0c00861. Epub 2020 May 18.
Herein, we report a protocol for visible-light-mediated allylation reactions between unactivated alkyl iodides and allyl sulfones under mild conditions with catalysis by inexpensive and readily available Mn(CO). This protocol is compatible with a wide array of sensitive functional groups and has a broad substrate scope with regard to both alkyl iodides and allyl sulfones.
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