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基于特殊医疗应用的 SiO₂/CMC/Ag 杂化材料的简便合成:源自废弃生物质(甘蔗渣)

Facile Synthesis of SiO₂/CMC/Ag Hybrids Derived from Waste Biomass (Sugarcane Bagasse) Having Special Medical Application.

机构信息

Department of Chemical Engineering, Motilal Nehru National Institute of Technology, Allahabad 211004, Uttar Pradesh, India.

Department of Chemical and Biomolecular Engineering, Yonsei University, 262 Seoul 120-749, Republic of Korea.

出版信息

J Nanosci Nanotechnol. 2020 Oct 1;20(10):6413-6421. doi: 10.1166/jnn.2020.18509.

Abstract

This research is focused on the use of sol gel technique to synthesize amorphous SiO₂ hybrids derived from lab made CMC (made from sugarcane bagasse) and tetraethoxysilane (TEOS) comprising silver nanoparticles (Ag-NPs). The dominant absorption peak in the order of 425 nm confirms the presence of Ag-NPs hybrid group owing to the surface Plasmon resonance (SPR). Ag-NPs hybrid characterization of was performed by Ultra violet-visible spectra (UV-Vis), Scanning electronic microscopy (SEM), Transmission electron microscopy (TEM), Particle size analyser (PSA), Energy Dispersive X-ray spectroscopy (EDX), X-ray diffractometer (XRD) and Fourier transform infrared spectroscopy (FTIR). The antibacterial action of Ag-NPs in contrast to Gram-negative bacteria (Escherichia coli) (ATCC 433) and Gram-positive bacteria (Bacillus subtilis) (ATCC 1688) was analyzed by using the method of agar disk diffusion technique. Ag-NPs hybrids extracted from lab-made CMC confirm higher adverse bacterial action through Gram-positive bacteria as well as Gram-negative bacteria related to synthetic CMC acquired from the market.

摘要

本研究专注于使用溶胶-凝胶技术合成由实验室制备的羧甲基纤维素(来自甘蔗渣)和正硅酸乙酯(TEOS)制备的无定形 SiO₂ 杂化体,其中包含银纳米粒子(Ag-NPs)。由于表面等离子体共振(SPR),在 425nm 左右的顺序中存在 Ag-NPs 杂化基团的主要吸收峰。Ag-NPs 杂化的特性通过紫外可见光谱(UV-Vis)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、粒径分析仪(PSA)、能量色散 X 射线光谱(EDX)、X 射线衍射仪(XRD)和傅里叶变换红外光谱(FTIR)进行了表征。通过琼脂盘扩散技术分析了 Ag-NPs 对革兰氏阴性菌(大肠杆菌)(ATCC 433)和革兰氏阳性菌(枯草芽孢杆菌)(ATCC 1688)的抗菌作用。从实验室制备的 CMC 中提取的 Ag-NPs 杂化物证实了对革兰氏阳性菌和革兰氏阴性菌的更高的不良细菌作用,这与从市场上获得的合成 CMC 有关。

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