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具有纳米纹理金属背反射器的柔性薄膜非晶硅太阳能电池中的光传播

Light Propagation in Flexible Thin-Film Amorphous Silicon Solar Cells with Nanotextured Metal Back Reflectors.

作者信息

Cao Shuangying, Yu Dongliang, Lin Yinyue, Zhang Chi, Lu Linfeng, Yin Min, Zhu Xufei, Chen Xiaoyuan, Li Dongdong

机构信息

CAS Key Lab of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 99 Haike Road, Zhangjiang Hi-Tech Park, Pudong, Shanghai 201210, China.

University of Chinese Academy of Sciences, 19 Yuquan Road, Beijing 100049, China.

出版信息

ACS Appl Mater Interfaces. 2020 Jun 10;12(23):26184-26192. doi: 10.1021/acsami.0c05330. Epub 2020 May 26.

Abstract

Nanostructured metal back reflectors (BRs) are playing an important role in thin-film solar cells, which facilitates an increased optical path length within a relatively thin absorbing layer. In this study, three nanotextured plasmonic metal (copper, gold, and silver) BRs underneath flexible thin-film amorphous silicon solar cells are systematically investigated. The solar cells with BRs demonstrate an excellent light harvesting capability in the long-wavelength region. With the combination of hybrid cavity resonances, horizontal modes, and surface plasmonic resonances, more incident light is coupled into the photoactive layer. Compared to the reference cells, the three devices with plasmonic BRs show lower parasitic absorptions with different individual absorption distributions. Both experimental and simulated results indicate that the silver BR cells delivered the best performance with a promising power conversion efficiency of 7.26%. These rational designs of light harvesting nanostructures provide guidelines for high-performance thin-film solar cells and other optoelectronic devices.

摘要

纳米结构金属背反射器(BRs)在薄膜太阳能电池中发挥着重要作用,它有助于在相对较薄的吸收层内增加光程长度。在本研究中,系统地研究了柔性薄膜非晶硅太阳能电池下方的三种纳米纹理化等离子体金属(铜、金和银)背反射器。带有背反射器的太阳能电池在长波长区域表现出优异的光捕获能力。通过混合腔共振、水平模式和表面等离子体共振的结合,更多的入射光被耦合到光活性层中。与参考电池相比,具有等离子体背反射器的三个器件表现出较低的寄生吸收,且具有不同的个体吸收分布。实验和模拟结果均表明,银背反射器电池表现最佳,具有7.26%的可观功率转换效率。这些光捕获纳米结构的合理设计为高性能薄膜太阳能电池和其他光电器件提供了指导。

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