VUV photoionization dynamics of the C buckminsterfullerene: 2D-matrix photoelectron spectroscopy in an astrophysical context.

We present the photoionization dynamics of the C buckminsterfullerene from threshold up to 14.0 eV recorded with VUV synchrotron radiation at the DESIRS beamline at the SOLEIL synchrotron. The recorded data is obtained using a double-imaging photoelectron photoion coincidence spectrometer and is presented as a two-dimensional photoelectron matrix which contains a wealth of spectroscopic data. We present these data in an astrophysical context which relates to (i) the threshold photoelectron spectrum which is compared to data relevant to the diffuse interstellar bands (DIBs), (ii) the kinetic photoelectron distribution at the Lyman-α line which is relevant to the dominant heating source in the ISM, and (iii) the absolute photoionization cross section of C up to approx. 10.5 eV. The photoelectron spectrum implies that the symmetry of the ground state is different than previous theoretical models have predicted, and this result is discussed in context of recent experimental and theoretical findings. Also presented are partial photoionization cross sections of the first two photoelectron bands and their anisotropy parameters. These data are compared with previous theoretical values and discussed where appropriate.