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Transport properties of AgI doped silver molybdate superionic glass-nanocomposites.

作者信息

Bhattacharya S, Ghosh A

机构信息

Department of Solid State Physics and UNANST-DST, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700 032, India.

出版信息

J Phys Condens Matter. 2005 Sep 21;17(37):5655-5662. doi: 10.1088/0953-8984/17/37/004.

DOI:10.1088/0953-8984/17/37/004
PMID:32397039
Abstract

We have reported the dc conductivity as well as the ac conductivity in the frequency range 10 Hz-2 MHz for xAgI-(1- x)(0.5AgO-0.5MoO), glass-nanocomposites in the temperature range 100-303 K. We have compared the conductivity and its activation energy for the molybdate nanocomposites with those of the borate and phosphate glasses. We have analysed the ac conductivity using the power law model. We have observed that both the dc conductivity and the crossover frequency obtained from the power law model show an activated behaviour. We have also observed that the power law exponent is almost independent of AgI doping content. Furthermore, the concentration of the mobile Ag ions is found to be independent of temperature as well as the AgI content in the compositions.

摘要

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