[BO] 作为硼中心氨基甲酸酯和羧酸酯等排体生成的前体。
[BO ] as a Synthon for the Generation of Boron-Centered Carbamate and Carboxylate Isosteres.
机构信息
Department of Chemistry, University of Bath, Bath, BA2 7AY, UK.
出版信息
Angew Chem Int Ed Engl. 2020 Aug 3;59(32):13628-13632. doi: 10.1002/anie.202005674. Epub 2020 Jun 4.
Abstract
Oxoborane carbamate and carboxylate analogues result from the in situ trapping of [BO ] produced by elimination of 2,3-dimethyl-2-butene from a pinacolatoboryl anion.
摘要
偕氧硼烷氨基甲酸酯和羧酸酯类似物是通过消除 2,3-二甲基-2-丁烯从偕频哪醇硼酸根阴离子生成的[BO]原位捕获得到的。
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