Kim Hyeong Jun, Paquin Lindsay, Barney Christopher W, So Soonyong, Chen Baohong, Suo Zhigang, Crosby Alfred J, Hayward Ryan C
Polymer Science and Engineering Department, University of Massachusetts, Amherst, MA, 01003, USA.
Energy Materials Research Center, Korea Research Institute of Chemical Technology, Daejeon, 34114, South Korea.
Adv Mater. 2020 Jun;32(25):e2000600. doi: 10.1002/adma.202000600. Epub 2020 May 17.
Electroadhesion provides a simple route to rapidly and reversibly control adhesion using applied electric potentials, offering promise for a variety of applications including haptics and robotics. Current electroadhesives, however, suffer from key limitations associated with the use of high operating voltages (>kV) and corresponding failure due to dielectric breakdown. Here, a new type of electroadhesion based on heterojunctions between iono-elastomer of opposite polarity is demonstrated, which can be operated at potentials as low as ≈1 V. The large electric field developed across the molecular-scale ionic double layer (IDL) when the junction is placed under reverse bias allows for strong adhesion at low voltages. In contrast, under forward bias, the electric field across the IDL is destroyed, substantially lowering the adhesion in a reversible fashion. These ionoelastomer electroadhesives are highly efficient with respect to the force capacity per electrostatic capacitive energy and are robust to defects or damage that typically lead to catastrophic failure of conventional dielectric electroadhesives. The findings provide new fundamental insight into low-voltage electroadhesion and broaden its possible applications.
电粘附提供了一种利用施加的电势快速且可逆地控制粘附力的简单方法,为包括触觉和机器人技术在内的各种应用带来了希望。然而,目前的电粘附材料存在与使用高工作电压(>kV)相关的关键限制,以及由于介电击穿导致的相应失效问题。在此,展示了一种基于相反极性离子弹性体之间异质结的新型电粘附,其可在低至约1 V的电势下运行。当异质结处于反向偏置时,在分子尺度离子双层(IDL)上产生的大电场允许在低电压下实现强粘附。相比之下,在正向偏置下,IDL上的电场被破坏,以可逆方式大幅降低粘附力。这些离子弹性体电粘附材料在每静电电容能量的力容量方面效率很高,并且对通常导致传统介电电粘附材料灾难性失效的缺陷或损伤具有鲁棒性。这些发现为低电压电粘附提供了新的基本见解,并拓宽了其可能的应用范围。